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Generally speaking, you can select whatever the CPU thinks its "virtual" core count is without issue. The list we give is up to double what the core count is, so getting a 32 core box you should be able to select 32 on there.
I'm not an expert on all the chipsets, but I can't imagine either of them having any trouble with the game. I mean, I'm sure the better one will be better, but whether it's noticeably better, I can't say.
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